Preparation and characterization of carboxymethyl cellulose/poly (ethylene glycol) -rosin pentaerythritolester polymeric nanoparticles: Role of intrinsic viscosity and surface morphology

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dc.authorid0000-0002-8368-4609en_US
dc.authorid0000-0003-1392-5056en_US
dc.authorid0000-0001-6115-4458en_US
dc.authorid0000-0001-8710-5750en_US
dc.authorid0000-0001-6788-1605en_US
dc.authorid0000-0001-6906-9880en_US
dc.authorid0000-0002-4347-1190en_US
dc.authorid0000-0002-9662-8390en_US
dc.contributor.authorKarakuş, Selcan
dc.contributor.authorIlgar, Merve
dc.contributor.authorTan, Ezgi
dc.contributor.authorKahyaoğlu, İbrahim Mizan
dc.contributor.authorTaşaltın, Nevin
dc.contributor.authorAlbayrak, İnci
dc.contributor.authorİnsel, Mert Akın
dc.contributor.authorKilislioğlu, Ayben
dc.date.accessioned2024-07-12T20:58:46Z
dc.date.available2024-07-12T20:58:46Z
dc.date.issued2020en_US
dc.departmentFakülteler, Mühendislik ve Doğa Bilimleri Fakültesi, Elektrik-Elektronik Mühendisliği Bölümüen_US
dc.description.abstractPolymeric nanoparticles gained importance due to their excellent chemical, physical and biological properties. Herein, novel sonochemical synthesized polymeric nanoparticles were constructed based on carboxymethyl cellulose (CMC)/poly (ethylene glycol) (PEG) polymer blend matrix and rosin pentaerythritolester (RE). Determining the rheology of the novel nanostructure by using dilute solution viscometer (DSV) method was aimed in this paper. This paper was aimed at to determine on the rheology of the novel nanostructure using the dilute solution viscometer (DSV) method.The influence of the temperature, mass ratio, and salt on the intrinsic viscosity of the synthesized CMC/PEG-RE nanoparticles was investigated and its physico-chemical properties were optimized using different mathematical equations such as Huggins, Kraemer, Tanglertpaibul-Rao, Higiro and Rao. The Krigbaum-Wall parameter, Berry number and dimensionless parameter were calculated to understand the degree of miscibility and the synergistic interaction of nanostructures. The Huggins was found to be the most suitable model with the highest correlation constant (R2: 0.94-0.99), and the intrinsic viscosity (22.2-23.4 dl/g). The surface morphology and chemical analysis of the polymeric nanoparticles were evaluated by Fourier-transform infrared spectroscopy (FTIR) and scanning transmission electron microscope (STEM). The results provided a better understanding of RE interactions in CMC/PEG polymer blends and colud be a promising nanocarrier for biomedical applications.en_US
dc.identifier.citationKarakuş, S., Ilgar, M., Tan, E., Kahyaoğlu, İ. M., Taşaltın, N., Albayrak, İ., İnsel, M. A. ve Kilislioğlu, A. (2020). Surfaces and Interfaces. Elsevier. 21, s. 1-10.en_US
dc.identifier.doi10.1016/j.surfin.2020.100642
dc.identifier.endpage10en_US
dc.identifier.issn2468-0230
dc.identifier.scopus2-s2.0-85089823193en_US
dc.identifier.scopusqualityQ1en_US
dc.identifier.startpage1en_US
dc.identifier.urihttps://www.sciencedirect.com/science/article/pii/S2468023020306349
dc.identifier.urihttps://doi.prg/10.1016/j.surfin.2020.100642
dc.identifier.urihttps://hdl.handle.net/20.500.12415/3221
dc.identifier.volume21en_US
dc.identifier.wosWOS:000606825900007en_US
dc.identifier.wosqualityQ1en_US
dc.indekslendigikaynakWeb of Science
dc.indekslendigikaynakScopus
dc.language.isoenen_US
dc.publisherElsevieren_US
dc.relation.ispartofSurfaces and Interfacesen_US
dc.relation.publicationcategoryUluslararası Hakemli Dergide Makale - Kurum Öğretim Elemanıen_US
dc.rightsinfo:eu-repo/semantics/openAccessen_US
dc.snmzKY03452
dc.subjectPolymeric nanoparticleen_US
dc.subjectViscosityen_US
dc.subjectSurface morphologyen_US
dc.subjectInterfacial interactionsen_US
dc.subjectPolymer miscibilityen_US
dc.subjectRosin pentaerythritol esteren_US
dc.titlePreparation and characterization of carboxymethyl cellulose/poly (ethylene glycol) -rosin pentaerythritolester polymeric nanoparticles: Role of intrinsic viscosity and surface morphologyen_US
dc.typeArticle
dspace.entity.typePublication

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