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Yayın Effect of Mn, Ni, Co transition metal ratios in lithium rich metal oxide cathodes on lithium ion battery performance(Elsevier, 2020) Çetin, Büşra; Camtakan, Zeyneb; Yuca, NeslihanLithium rich layered metal oxide is a high energy density cathode material for new generation lithium ion batteries (LIBs). This material has Li [Li1/3Mn2/3]O-2 and LiMO2 (M: Ni, Co, Mn, Al etc.) structure and exhibit higher irreversible capacity and cycle life than conventional cathode materials. In this study, the stoichiometry of metals in the lithium rich cathode material formulation was investigated by changing Mn, Ni and Co ratios. Li1.2Mn0.49+xCo0.2-2xNi0.2-2xAl0.02O2 (x = 0, 0.01, 0.02, 0.03). formulation was used and the prepared lithium rich cathode active powders were structurally characterized by XRD, ICP and NAA. Li-rich cathodes were tested by electrochemical methods, too. (c) 2019 Elsevier Ltd. All rights reserved. Selection and peer-review under responsibility of the scientific committee of the E-MRS Fall Meeting, 2019. All rights reserved.Yayın Self-healing systems in silicon anodes for li-lon batteries(Materials, 2022) Yuca, Neslihan; Kalafat, İlknur; Güney, Emre; Çetin, Büşra; Taşkın, Ömer S.Self-healing is the capability of materials to repair themselves after the damage has occurred, usually through the interaction between molecules or chains. Physical and chemical processes are applied for the preparation of self-healing systems. There are different approaches for these systems, such as heterogeneous systems, shape memory effects, hydrogen bonding or covalent–bond interaction, diffusion, and flow dynamics. Self-healing mechanisms can occur in particular through heat and light exposure or through reconnection without a direct effect. The applications of these systems display an increasing trend in both the R&D and industry sectors. Moreover, self-healing systems and their energy storage applications are currently gaining great importance. This review aims to provide general information on recent developments in self-healing materials and their battery applications given the critical importance of self-healing systems for lithium-ion batteries (LIBs). In the first part of the review, an introduction about self-healing mechanisms and design strategies for self-healing materials is given. Then, selected important healing materials in the literature for the anodes of LIBs are mentioned in the second part. The results and future perspectives are stated in the conclusion section.